"I think we won the race here with Richard Petty Motorsports a couple, three years ago, so some of the guys know how to win here also. We have a driver we think that gave one of them away out here so it is time he got one back for us!"
Ambrose's qualifying lap was 75.203s (95.262mph) on the 1.99-mile road course was 0.154s faster than that of Jeff Gordon and was a new qualifying record for the NASCAR-configuration of the raceway.
"I was very pleased with the lap," said Gordon of his own effort, which was the last qualifying run of anyone on Friday. "It was a very solid lap, the best lap I've had here in a number of years and I'm very pleased.
"I know we got second ... Marcos put down one heck of a lap and that was going to be tough to beat," he admitted. "I wasn't going to allow myself to be reeled in too much to try to get so aggressive to shoot for the pole to where we ruined a good, solid qualifying effort. So I tried to attack areas that I felt the car had it in it, and showed that in practice, and the car stuck; and other areas where I felt like if I attacked I could go over the edge. I was making sure that I didn't do that."
Gordon's lap ended up clocked at 75.357s, 0.154s off Ambrose's time but still ahead of Gordon's own team mate Jimmie Johnson who claimed third place and will start Sunday's Toyota/Save Mart 350 race on the second row of the grid alongside Greg Biffle.
The third row was an all-Michael Waltrip Racing affair, with Martin truex Jr. just pipping his team mate Clint Bowyer for the better spot, while behind them on the fourth row it was a Busch family reunion with Kyle Busch starting alongside his older brother Kurt.
Matt Kenseth and Ryan Newman round out the top ten, with Carl Edwards just outside in 11th and due to start the race alongside Juan Montoya, himself something of a road course specialist after his years in F1 and a previous Sonoma winner back in 2007.
"It was okay," said the Colombian. "It was really good the first part of the lap. We just got too loose in the fast corners; the last two right-handers, I was just way too loose. But it was fun.
"I lost a lot of time where I got sideways," he admitted. "Where you should be wide-open I'm half-throttle, drifting. And drifting is not fast!"
Last week's race winner Dale Earnhardt Jr. was back down to earth somewhat, not a natural road racer and not able to match the performances of his Hendrick team mates on Friday as he qualified down in 19th.